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Article
Publication date: 2 February 2024

Reasmy Raj, Amirul Syafiq, Vengadaesvaran Balakrishnan, Shakeel Ahmad, Nasrudin Abd Rahim, Pouya Hassandarvish, Sazaly Abu Bakar and A.K. Pandey

This paper aims to fabricate a polymer-based polyethylene glycol (PEG) coating with acrylic resin as a binder that can show antiviral activity against the feline coronavirus…

Abstract

Purpose

This paper aims to fabricate a polymer-based polyethylene glycol (PEG) coating with acrylic resin as a binder that can show antiviral activity against the feline coronavirus (FCov) on the glass substrate.

Design/methodology/approach

The PEG/acrylic coating systems of different weight percentages were coated on the glass substrates using the spray-coating method and cured at room temperature for 24 h.

Findings

The coating system containing 20 Wt.% of PEG exhibits the highest antiviral activities as high as 99.9% against FCov compared with other samples.

Research limitations/implications

Findings will be useful in the development of antiviral coating for PPE fabrics by using the simple synthesis method.

Originality/value

Application of PEG as an antiviral agent in the antiviral coating system with high antiviral activities about 99.9%.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 22 November 2023

Khishn Kumar Kandiah, Vengadaesvaran Balakrishnan, Amirul Syafiq, Nasrudin Abd Rahim, Adarsh Kumar Pandey, Yee Seng Tan, Sanjay J Dhoble, Ramesh Kasi and Ramesh Subramaniam

There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low…

Abstract

Purpose

There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low photoluminescence (PL) properties. The purpose of this paper is to invent a better rare-earth-based pigment material as a spectral modifier with good luminescence properties to enhance the spectral response for photovoltaic panel application.

Design/methodology/approach

Different phosphor samples made of nano-calcium carbonate (CaCO3) with varied wt.% of the dopant Dysprosium doped calcium borophosphate (CBP/Dy) as (W0 – 0%, W1 – 3,85%, W2 – 7.41%, W3 –10.71% and W4 –13.79%) were prepared via the solid-state diffusion method at 600 °C for 6 h using a muffle furnace. The structural, morphological and luminescence properties of the CaCO3:CBP/Dy powder samples were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and PL test.

Findings

The XRD, SEM and FTIR results verified the crystalline formation, morphological behaviour and vibration bonds of synthesized CBP/Dy-doped CaCO3 powder samples. XRD pattern revealed that the synthesized powder samples exhibit crystalline structured materials, and SEM results showed irregular shape and porous-like structured morphologies. FTIR spectrum shows prominent bands at 712, 874 and 1,404 cm−1, corresponding to asymmetric stretching vibrations of CO32− groups and out-of-plane bending. PL characterization of CBP/Dy-doped CaCO3 (sample W) shows emission at 427 nm (λmax) under the excitation of 358 nm. The intensity of PL emission spectra drops due to the concentration quenching effect, while the maximum PL intensity is observed in the W3 phosphor powder system.

Research limitations/implications

This phosphor powder is expected to find out the potential application such as a spectral modifier which is applied to match the energy of photons with solar cell bandgap to improve spectral absorption and lead to better efficiency.

Originality/value

The introduction of a nano-CaCO3:CBP/Dy hybrid powder system with good luminescence properties to be used as spectral modifiers for solar cell application has been synthesized in the lab, which is a novel attempt.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 18 January 2023

Amirul Syafiq, Farah Khaleda Mohd Zaini, Vengadaesvaran Balakrishnan and Nasrudin Abd. Rahim

The purpose of this paper is to introduce the simple synthesis process of thermal-insulation coating by using three different nanoparticles, namely, nano-zinc oxide (ZnO)…

Abstract

Purpose

The purpose of this paper is to introduce the simple synthesis process of thermal-insulation coating by using three different nanoparticles, namely, nano-zinc oxide (ZnO), nano-tin dioxide (SnO2) and nano-titanium dioxide (TiO2), which can reduce the temperature of solar cells.

Design/methodology/approach

The thermal-insulation coating is designed using sol-gel process. The aminopropyltriethoxysilane/methyltrimethoxysilane binder system improves the cross-linking between the hydroxyl groups, -OH of nanoparticles. The isopropyl alcohol is used as a solvent medium. The fabrication method is a dip-coating method.

Findings

The prepared S1B1 coating (20 Wt.% of SnO2) exhibits high transparency and great thermal insulation property where the surface temperature of solar cells has been reduced by 13°C under 1,000 W/m2 irradiation after 1 h. Meanwhile, the Z1B2 coating (20 Wt.% of ZnO) reduced the temperature of solar cells by 7°C. On the other hand, the embedded nanoparticles have improved the fill factor of solar cells by 0.2 or 33.33%.

Research limitations/implications

Findings provide a significant method for the development of thermal-insulation coating by a simple synthesis process and low-cost materials.

Practical implications

The thermal-insulation coating is proposed to prevent exterior heat energy to the inside solar panel glass. At the same time, it can prevent excessive heating on the solar cell’s surface, later improves the efficiency of solar cell.

Originality/value

This study presents a the novel method to develop and compare the thermal-insulation coating by using various nanoparticles, namely, nano-TiO2, nano-SnO2 and nano-ZnO at different weight percentage.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 26 September 2022

Amirul Syafiq, Nasrudin Abd. Rahim, Vengadaesvaran Balakrishnan and A.K. Pandey

This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium…

Abstract

Purpose

This paper introduced the simple synthesis process of self-cleaning coating with fog-resistance property using hydrophobic polydimethylsiloxane (PDMS) polymer and nano-calcium carbonate (nano-CaCO3) and titanium dioxide (TiO2).

Design/methodology/approach

The synthesis method of PDMS/nano-CaCO3-TiO2 is based on sol-gel process. The crosslinking between PDMS and nanoparticles is driven by the covalent bond at temperature of 50°C. The 3-Aminopropyltriethoxysilane is used as binder for nanoparticles attachment in polymer matrix. Two fabrication methods are used, which are dip- and spray-coating methods.

Findings

The prepared coated glass fulfilled the requirement of standard self-cleaning and fog-resistance performance. For the self-cleaning test BS EN 1096-5:2016, the coated glasses exhibited the dust haze value around 20%–25% at tilt angle of 10°. For the antifog test, the coated glasses showed the fog haze value were below 2% and the gloss value were above 85%. The obtained results completely achieved the standard antifog value ASTM F659-06 protocol.

Research limitations/implications

Findings will provide an infrastructure support for the building glass to enhance building’s energy efficiency, cleaning performance and friendly environment.

Practical implications

This study proposed the simple synthesis method using hydrophobic polymer and nano-CaCO3 and nano-TiO2, which can achieve optimum self-cleaning property at low tilt angle and fog-resistance performance for building glass.

Social implications

The research findings have high potential for building company, cleaning building company and government sector. The proposed project capable to reduces the energy consumption about 20% per annum due to labor cost, time-consuming and safety during manual cleaning.

Originality/value

The novel method to develop self-cleaning coating with fog-resistance using simple synthesis process and fabrication method for building glass application.

Article
Publication date: 30 September 2022

Amirul Syafiq, Vengadaesvaran Balakrishnan and Nasrudin Abd. Rahim

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong…

Abstract

Purpose

This paper aims to design the nano-titanium dioxide (TiO2) coating system which has superhydrophilic property, self-cleaning mechanism and antifog property as well as strong adhesion on glass substrate.

Design/methodology/approach

Two hydrophilic materials have been used such as TiO2 nanoparticles as fillers and hydrophilic copolymer, Pluronic F-127 by using simple sol–gel approach. The prepared solution was applied onto glass through dip- and spray-coating techniques and then left for drying at ambient temperature.

Findings

The nano-TiO2 superhydrophilic coating has achieved the water contact angle of 4.9° ± 0.5°. The superhydrophilic coating showed great self-cleaning effect against concentrated syrup and methylene blue where thin layer of water washes the dirt contaminants away. The nano-TiO2 coating exhibits great antifog performance that maintains high transparency of around 89% when the coated glass is placed above hot-fog vapor for 10 min. The fog droplets were condensed into water film which allowed the transmission of light through the glass. The strong adhesion of coated glass shows no total failure at scratch profile when impacted with scratch load of 500, 800 and 1,200 mN.

Research limitations/implications

Findings will be useful in the development of self-cleaning superhydrophilic coating that is applicable on building glass and photovoltaic panel.

Practical implications

The developed nano-TiO2 coating is developed by the combination of hydrophilic organic copolymer–inorganic TiO2 network to achieve great superhydrophilic property, optimum self-cleaning ability and supreme antifog performance.

Social implications

The findings will be useful for residents in building glass window where the application will reduce dust accumulation and keep the glass clean for longer period.

Originality/value

The synthesis of nano-TiO2 superhydrophilic coating which can be sprayed on large glass panel and cured at ambient temperature.

Article
Publication date: 22 November 2018

A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan, Syed Shahabuddin and Nasrudin Abd Rahim

This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Abstract

Purpose

This paper aims to investigate the thermal stability and hydrophobicity of difference alkyl chain of silanes with silicon (Si) micro- and nanoparticles.

Design/methodology/approach

Sol-gel methods have been used to design superhydrophobic glass substrates through surface modification by using low-surface-energy Isooctyl trimethoxysilane (ITMS) and Ethyl trimethoxysilane (ETMS) solution. Hierarchical double-rough scale solid surface was built by Si micro- and nanoparticles to enhance the surface roughness. The prepared sol was applied onto glass substrate using dip-coating method and was dried at control temperature of 400°C inside the tube furnace.

Findings

The glass substrate achieved the water contact angle as high as 154 ± 2° and 150.4 ± 2° for Si/ITMS and Si/ETMS films, respectively. The Si/ITMS and Si/ETMS also were equipped with low sliding angle as low as 3° and 5°, respectively. The Si micro- and nanoparticles in the coating system have created nanopillars between them, which will suspend the water droplets. Both superhydrophobic coatings have showed good stability against high temperature up to 200°C as there are no changes in WCA shown by both coatings. Si/ITMS film sustains its superhydrophobicity after impacting with further temperature up to 400°C and turns hydrophobic state at 450°C.

Research limitations/implications

Findings will be useful to develop superhydrophobic coatings with high thermal stability.

Practical implications

Sol method provides a suitable medium for the combination of organic-inorganic network to achieve high hydrophobicity with optimum surface roughness.

Originality/value

Application of different alkyl chain groups of silane resin blending with micro- and nanoparticles of Si pigments develops superhydrophobic coatings with high thermal stability.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 31 December 2018

A. Syafiq, A.K. Pandey, Vengadaesvaran Balakrishnan and Nasrudin Abd Rahim

The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass…

Abstract

Purpose

The paper aims to investigate the effect of Degussa P-25 Titanium Dioxide (TiO2) nanoparticles on hydrophobicity and self-cleaning ability as a single organic coating on glass substrate.

Design/methodology/approach

Two methods have been used to enhance the hydrophobicity on glass substrates, namely, surface modification by using low surface energy isooctyltrimethoxysilane (ITMS) solution and construction of rough surface morphology using Degussa P-25 TiO2 nanoparticles with simple bottom-up approach. The prepared sol was applied onto glass substrate using dip-coating technique and stoved in the vacuum furnace 350°C.

Findings

The ITMS coating with nano TiO2 pigment has modified the glass substrate surface by achieving the water contact angle as high as 169° ± 2° and low sliding angle of 0° with simple and low-cost operation. The solid and air phase interface has created excellent anti-dirt and self-cleaning properties against dilute ketchup solution, mud and silicon powder.

Research limitations/implications

Findings will be useful in the development of self-cleaning and anti-dirt coating for photovoltaic panels.

Practical implications

Sol method provides the suitable medium for the combination of organic–inorganic network to achieve high superhydrophobicity and optimum self-cleaning ability.

Originality/value

Application of blended organic–inorganic sol as self-cleaning and anti-dirt coating film.

Details

Pigment & Resin Technology, vol. 53 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 20 September 2019

Farah Khaleda Mohd Zaini, Vengadaesvaran Balakrishnan, A. Syafiq, Nasrudin Abd. Rahim, A.K. Pandey, Ramesh Kasi and Ramesh Subramaniam

The purpose of this paper is to implement coating system by varying the amount of nano-sized titanium dioxide, (nano-TiO2) combined with various organic binders and to study the…

Abstract

Purpose

The purpose of this paper is to implement coating system by varying the amount of nano-sized titanium dioxide, (nano-TiO2) combined with various organic binders and to study the coating effects on the performance of solar cell in terms of temperature and efficiency.

Design/methodology/approach

Nano-TiO2 coatings are developed in two types of binder networks; the combination of methyltrimethoxy silane (MTMS) and nitric acid and the combination of 3-aminopropyl triethoxysilane (APTES) and MTMS. Overall, the formulations method was cost-effective, produces good transparency, clear and managed to dry at room temperature. The coating mixtures were applied onto the glass substrate by using the dip-coating method and the coated substrate were sent for several characterizations.

Findings

This study demonstrated that TiO2 nanoparticle coating in APTES/MTMS matrix showed a thermal-decreasing result on solar cells, where the cell temperature is reduced to 46.81°C (T2 coating type) from 55.74°C (without coating) after 1-h exposure under 1,000 W/m2 irradiance in a solar simulator. Contrary to prior works where solar cell coatings were reported to reduce the cell temperature at the expense of the cell efficiency, the results from this study reported an improved fill factor (FF) of solar cells. From the photovoltaic (PV) characteristics study, the FF for solar cells is increased by approximately 0.2, i.e. 33.3 per cent, for all coatings compared to the non-coated cell.

Research limitations/implications

Findings will be able to contribute in the development of temperature-reducing and efficiency-enhancing coating for PV panels.

Practical implications

A simple dip-coating method provides an even distribution of TiO2 nanoparticle coating on the glass panel, which is cost-effective and time-efficient to reduce the temperature of solar cell while maintaining its efficiency.

Originality/value

The ability of nano-TiO2 coatings with a simple fabrication method and the right solution to reduce the surface temperature of solar cells while improving the FF of the cells.

Details

Pigment & Resin Technology, vol. 49 no. 1
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 April 2020

Azimah Omar, Muhamad Saipul Fakir, Khairus Syifa Hamdan, Nurul Hidayah Rased and Nasrudin Abd. Rahim

The purpose of this paper is to investigate the chemical, optical and photovoltaic properties of titanium dioxide/reduced graphene oxide (TiO2/rGO) photoanodes immersed in natural…

Abstract

Purpose

The purpose of this paper is to investigate the chemical, optical and photovoltaic properties of titanium dioxide/reduced graphene oxide (TiO2/rGO) photoanodes immersed in natural Roselle and synthetic (N719) dyes for dye-sensitized solar cell (DSSC) application.

Design/methodology/approach

TiO2 mixed with rGO were doctor-bladed on fluorine doped tin oxide (FTO) glass substrate. The chemical and optical properties of TiO2/rGO photoanodes immersed in Roselle and N719 dyes were characterized using Fourier-transformed infrared (FTIR) and ultraviolet–visible (UV–vis) spectroscopies, respectively. The DSSC’s photovoltaic performances were tested using Visiontec Solar I-V tester at standard illumination of AM1.5 and irradiance level of 100 mW/cm2.

Findings

The presence of anthocyanin dye from Roselle flower was detected at 604 nm and 718 nm. TiO2/rGO+Roselle dye sample revealed the smallest energy gap of 0.17 eV for ease of electron movement from valence band to conduction band. The TiO2/rGO-based DSSC fabricated with Roselle dye had a power conversion efficiency, ƞ of 0.743 per cent higher than TiO2/rGO photoanode sensitized with N719 dye (0.334 per cent). The obtained J-V curves were analyzed by a single-diode model of Lambert W-function and manual optimization to determine the internal electrical parameters of the DSSC. The average and uncertainty values of Jsc and ƞ were evaluated at different Rsh range of 1362 Ω to 32 k Ω.

Research limitations/implications

Rs values were kept constant during optimization work.

Originality/value

New ideality factor of TiO2/rGO-based DSSC was re-determined around 0.9995.

Details

Pigment & Resin Technology, vol. 49 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 19 September 2022

Nurul Izzah Abdul Aziz, Husniza Husni and Nor Laily Hashim

The aim of this paper is to explore, analyse and summarise the potential tangible user interface (TUI) design features for dyslexics learning to read and spell.

Abstract

Purpose

The aim of this paper is to explore, analyse and summarise the potential tangible user interface (TUI) design features for dyslexics learning to read and spell.

Design/methodology/approach

This study adopts a systematic literature review method through a manual search of published papers from 2011. This systematic literature review consists of three main phases starting with planning the review, conducting the review and studying the selection and reporting the results.

Findings

As the result, 10 papers were found that are considered most applicable as they met the review criteria. Based on the 10 papers, 11 design features are found in the current TUIs design features implemented in the tangible system dedicated for dyslexia and reading. The 11 design features are viewed to be fundamental and useful for the groundwork towards designing and developing a comprehensive TUIs design specifically and exclusively meant for dyslexic children learning to read and spell.

Originality/value

A critical reading of past literature relating to the TUIs concept reveals that this concept still appears to be under-explored even though it was introduced two decades ago. This systematic literature review highlights directions for future research, involving the dyslexic children early in the design process towards the evaluation of the prototype and finally examining the outcome of TUIs on children's learning.

Details

The International Journal of Information and Learning Technology, vol. 39 no. 4
Type: Research Article
ISSN: 2056-4880

Keywords

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